Long term aging (Steel)
According to Mercury Magnetics this has the largest effect on transformers over time (as it relates to steel in older transformers) and depending on the amount of carbon, sulfur, oxygen and nitrogen...
http://en.wikipedia.org/wiki/Electrical_steel
Silicon significantly increases the electrical resistivity of the steel, which decreases the induced eddy currents and narrows the hysteresis loop of the material, thus lowering the core loss.[1] However, the grain structure hardens and embrittles the metal, which adversely affects the workability of the material, especially when rolling it. When alloying, the concentration levels of carbon, sulfur, oxygen and nitrogen must be kept low, as these elements indicate the presence of carbides, sulfides, oxides and nitrides. These compounds, even in particles as small as one micrometer in diameter, increase hysteresis losses while also decreasing magnetic permeability. The presence of carbon has a more detrimental effect than sulfur or oxygen. Carbon also causes magnetic aging when it slowly leaves the solid solution and precipitates as carbides, thus resulting in an increase in power loss over time. For these reasons, the carbon level is kept to 0.005% or lower. The carbon level can be reduced by annealing the steel in a decarburizing atmosphere, such as hydrogen.[2]
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Short term effects?
One possibility would be due to magnetic hysteresis effects.
(partial alignment of magnetic domains due to magnetic fields).. which could change the response and coupling in an OT ...Perhaps Zippy can elaborate if this is a possibility?
Here is a paper on aging affects on various insulators (includes Paper)
http://journals.tubitak.gov.tr/elektrik ... 0802-5.pdf
7. Conclusions
A series of accelerated ageing experiments has been investigated for oil/paper cellulose insulation system used
in transformers. Polarization and depolarization currents and recovery voltage of aged cellulose immersed in
oil were measured. The aim of tests was condition assessment of insulation system. The main properties of oil
and paper were studied. Electrical measurements show that both polarization and depolarization currents are
strongly influenced by ageing time and water content of oil and paper. The results have shown that maximum
recovery voltage of oil/paper insulation system and tensile strength of paper insulation in power transformers
vary significantly and consistently with respect to ageing time and ageing temperatures.
Good correlations have been obtained between the tensile strength of insulating paper with recovery
voltage of insulation system, total acid number (TAN), and water content in oil. The tensile strength results
have been used to predict how lifetime of insulating paper changes with temperature and time. Therefore
lifetime of paper has been estimated by using Arrhenius model. It can predict the life of paper for power
transformers at various operational temperatures.
Like Max suggest..The problem with these types of tests is how they actually affect tone in guitar amps will likely never be known without extensive testing and at great expense.. So IMO to ask for scientific evidence and how it effects tone is extremely difficult and due to all the variables involved,
BTW.. Those out there with degrees and doctorates on the subject, it would be nice to at least offer up some of the variables that might contribute to the changes in sound (or NOT) over time since it's been stated here and other sources that they notice it!..Perhaps this would give others some place to look if they want research it further..Also if some of this info I posted does not apply PLEASE state why you think so so we can advance the discussion..
So much for bowing out..Huh!
Tony