What I found was VERY helpful when first learning circuits was to actually read and memorize schematics, to this day I can take out a pen and paper and draw you a 5F6A Bassman, or an AB763 Deluxe reverb. The point is not in memorizing the minutia, but in understanding the role different components play within the circuit. I also found that after the first project that they're all about the same, IE there isn't a ton of difference between building a champ and a Bassman. For a first project I wouldn't reccommend building a High gain channel switcher or anything crazy like that, but if you're comfortable with your soldering skills, patient enough to triple check all your components for value, triple check all your solder connections and ground connections before firing it up you'll do fine-It's not rocket science, it's 1930's technology!! Read these:
Dave Funk's "Tube Amp Workbook"
the tech info section at
www.aikenamps.com
Both Gerald Weber books are worth a read, "Tube amp talk" and "a desk top reference of hip vintage guitar amps".
"Valve Amp" and the companion "Building Valve Amps" by Morgan Jones.
The other thing would be to build a David Allen Kit, they are built such that it is almost impossible to fail, and the Instructions are written for the lay person, in an easy to follow step by step format. I built one of his Class Act kits a few years ago and it is still one of my favorite amps to play-TOP quality for sure. The build process was easy and only took a couple of days, and I'm sure that it would have been an easy build for someone with little to no experience.